Removal of Boron from Simulated Iraqi Surface Water by Electrocoagulation Method

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Waleed M. Salih
Saadi K. Alnasri
Ali Abdulameer Al Abdalaali

Abstract

The removal of boron from aqueous solution was carried out by electrocoagulation (EC) using magnesium electrodes as anode and stainless steel electrodes as cathode. Several operating parameters on the removal efficiency of boron were investigated, such as initial pH, current density, initial boron ion concentration, NaCl concentration, spacing between electrodes, electrode material, and presence of carbonate concentration. The optimum removal efficiency of 91. 5 % was achieved at a current density of 3 mA/cm² and  pH = 7 using (Mg/St. St. ) electrodes, within 45 min of operating time. The concentration of NaCl was o. 1 g/l with a 0.5cm spacing between the electrodes. First and second order rate equation were applied to study adsorption kinetics. The adsorption process
follows second order kinetic model with good correlation. The energy consumption was evaluated for the optimum operating conditions. It was in the range of 1.296 to 1.944 Kwh/m3 . The overall expected increase in the operating cost of water treatment using membrane desalination facility (for example) will be about 20%.

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How to Cite
“Removal of Boron from Simulated Iraqi Surface Water by Electrocoagulation Method ” (2012) Journal of Engineering, 18(11), pp. 1266–1281. doi:10.31026/j.eng.2012.11.07.
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Articles

How to Cite

“Removal of Boron from Simulated Iraqi Surface Water by Electrocoagulation Method ” (2012) Journal of Engineering, 18(11), pp. 1266–1281. doi:10.31026/j.eng.2012.11.07.

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References

Al Gurany, A. J. M., Separation of oil from O/W emulsion by electroflotation technique, MSc. Thesis, University of Baghdad, 2009.

Christos C. and G. Chen, Electrochemistry for the Environment, Springer, New York, 2010, pp. 245-262.

Iraqi specifications for drinking water, 2009.

Kabay, N., Boron in seawater and methods for its separation — A review, Desalination 2010, doi:10. 1016/j. desal. 2010. 05. 033

Lawrence K. , Yung Tse, Nazih K. , Advanced Physicochemical Treatment Technologies, Humana Press, Totowa, New Jersey, 2007, pp. 64-65.

Nihal Bektas¸S. Oncel · H. Y. Akbulut, A. Dimoglo, Removal of boron by electrocoagulation, Environ Chem Lett, 2004, pp. 2:51–5.

Peter Holt, Geoffrey Barton, Cynthia Mitchell, EC as a wastewater treatment, The Third Annual Australian Environmental Engineering Research Event. 23-26 November Castlemaine, Victoria, 1999.

Saeid Azizian, Kinetic models of sorption: a theoretical analysis, Journal of Colloid and Interface Science 276 2004, pp. 47–52.

Subramanyan Vasudevan, Jothinathan Lakshmi, Sagayaraj Margrat Sheela, Optimization of the process parameters for the removal of boron from drinking water by electrocoagulation – a clean technology, J Chem Technol Biotechnol (2010), DOI 10. 1002/jctb. 2382.

USEPA. 2008. Regulatory Determinations Support Document for Selected Contaminants from the Second Drinking Water Contaminant Candidate List (CCL 2). EPA Report 815-R-08-012. June.

World Health Organization, Guidelines for Drinking-Water Quality, 3nd ed. , pp. 313, 314; Geneva, 2008.

Yonglan Xu and Jia-Qian Jiang, Technologies for Boron Removal, Ind. Eng. Chem. Res. 2008, 47, pp. 16-24.

Yilmaz A. E., Recep Boncukcuo˘glu, Muhtar Kocakerim M., A quantitative comparison between electrocoagulation and chemical coagulation for boron removal from boron-containing solution, Journal of Hazardous Materials, 2007, 149, pp. 475–481.

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