جيلاتين مُعدَّل بالتشابك لإزالة صبغة الغروب الأصفر: التحضير، التوصيف، وتقييم الأداء
محتوى المقالة الرئيسي
الملخص
يُعدّ الجيلاتين مادة قيّمة تتميز ببنية ثلاثية الأبعاد معقدة. في هذه الدراسة، تم تحسين الجيلاتين بإضافة الجلوتارالدهيد (GTA) لتعزيز قدرته على امتزاز الأصباغ من المياه الملوثة. وتمت دراسة طبيعة الجيلاتين المعدّل بالجلوتارالدهيد من حيث خصائصه الكيميائية وسلوكه الحراري، بالإضافة إلى دراسة حركية وديناميكية امتزاز صبغة الغروب الأصفر. أُجريت تجارب الامتزاز تحت ظروف مختلفة شملت كمية المادة المازّة المضافة، وتركيز الصبغة الابتدائي، ودرجة الحرارة. وأظهرت النتائج أن كمية الصبغة الممتزة بواسطة الجيلاتين المتشابك بالجلوتارالدهيد (GTA-GE) والجيلاتين غير المعدّل (GE) تزداد بزيادة التركيز الابتدائي للصبغة، بينما تنخفض بزيادة كمية المادة المازّة المستخدمة. تم تحقيق حالة الاتزان عند قيمة pH مقدارها 4، وكمية مادة مازّة مقدارها 100 ملغم، خلال زمن تماس بلغ 80 دقيقة. وتراوحت كفاءة إزالة الصبغة بين 88.4–99.8% للجيلاتين المتشابك بالجلوتارالدهيد، وبين 83–96% للجيلاتين غير المعدّل. تم تحليل بيانات الاتزان باستخدام نموذجي Freundlich وLangmuir للامتزاز، وأظهر نموذج Freundlich أفضل مطابقة للبيانات، مما يشير إلى ملاءمته لوصف عملية الامتزاز وتعدد مواقع الارتباط على السطح. كما أظهرت دراسة الحركية أن امتزاز صبغة الغروب الأصفر على الجيلاتين يتبع نموذج pseudo-second order، مما يدل على أن عملية الامتزاز يغلب عليها الطابع الفيزيائي. وأوضحت الديناميكية الحرارية أن العملية طاردة للحرارة وتلقائية الحدوث، استنادًا إلى القيم السالبة لكل من التغير في الطاقة الحرة والتغير في الإنثالبي، مع تسجيل قيمة للتغير في الإنتروبي بلغت (kJ/k. mol0.021). ويشير ذلك إلى ازدياد درجة الانتظام عند السطح البيني بين الطور الصلب والمحلول أثناء عملية الامتزاز.كما بيّنت النتائج إمكانية إعادة استخدام المادة المازّة لأربع دورات متتالية مع انخفاض في كفاءة الإزالة.
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