Improvement Marshall Properties of Hot Mix Asphalt Concrete Using Polyphosphoric Acid

Main Article Content

Marwa Jawad Badr
Mohammed Qadir Ismael

Abstract

Modified asphalt is considered one of the alternatives to address the problems of deficiencies in traditional asphalt concrete, as modified asphalt addresses many of the issues that appear on the pavement layers in asphalt concrete, resulting from heavy traffic and vehicles loaded with loads that exceed the design loads and the large fluctuations in the daily and seasonal temperatures of asphalt concrete. The current study examined the role of polyphosphoric acid (PPA) as a modified material for virgin asphalt when it was added in different proportions (1%, 2%, 3%, 4%) of the asphalt weight. The experimental program includes the volumetric characteristics associated with the Marshall test, the physical properties, and the FTIR spectroscopy examination of virgin asphalt and polyphosphoric acid (PPA) modified asphalt. This study showed that mixtures with modified asphalt using polyphosphoric acid (PPA) by 3% achieved the typical Marshall properties at the optimal asphalt content of 4.8%, recording a 10% decrease in the optimum asphalt content for the mixtures made with virgin (unmodified) asphalt, whose proportion was 4.9% is the optimum asphalt content. PPA is available in the local markets and is considered cheaper than polymers. It is also regarded as economical as it reduces the optimum content of asphalt.

Article Details

How to Cite
“Improvement Marshall Properties of Hot Mix Asphalt Concrete Using Polyphosphoric Acid” (2024) Journal of Engineering, 30(01), pp. 124–139. doi:10.31026/j.eng.2024.01.08.
Section
Articles

How to Cite

“Improvement Marshall Properties of Hot Mix Asphalt Concrete Using Polyphosphoric Acid” (2024) Journal of Engineering, 30(01), pp. 124–139. doi:10.31026/j.eng.2024.01.08.

Publication Dates

References

AASHTO, R30., 2019. Standard practice for mixture conditioning of hot mix asphalt. American Association of State and Highway Transportation Officials, 02, pp. 1–5.

Al-Hadidy, A.R.I., Al-Kazzaz, Z.A., and Ali, A.A.M., 2020. Deterministic extensional viscosity and cracking index of polypropylene-modified-asphalt binder. Tikrit Journal of Engineering Sciences, 27(1), pp.25-29. Doi:10.25130/tjes.27.1.04

Al-Saadi, A.A., and Ismael, M.Q., 2023. Improvement of Moisture Susceptibility for Asphalt Mixture with Ceramic Fiber. Journal of Engineering, 29(4), pp.78-91. Doi:10.31026/j.eng.2023.04.05

Baumgardner, G., Hajj, E. Y., Aschenbrener, T. B., and Hand, A. J., 2023. Responsible use of polyphosphoric acid (PPA) modification of asphalt binders.‏ Department of Civil and Environmental Engineering University of Nevada 1664 North Virginia Street Reno, NV 89557. http://www.ntis.gov

De Filippis, P., Giavarini, C., and Scarsella, M., 1995. Improving the aging resistance of straight-run bitumens by addition of phosphorus compounds. Fuel, 74(6), pp. 836-841. Doi:10.1016/0016-2361(95)00015-W

Du, J., Ai, C., An, S., and Qiu, Y., 2020. Rheological properties at low temperatures and chemical analysis of a composite asphalt modified with polyphosphoric acid. Journal of Materials in Civil Engineering, 32(5), p.04020075. Doi:10.1061/ (ASCE)MT.1943-5533.0003123.

Fattah, M.Y., Abdulkhabeer, W., and Hilal, M.M., 2021. Characteristics of asphalt binder and mixture modified with waste polypropylene. Engineering and Technology Journal, 39(8), pp.1224-1230. Doi:10.30684/etj.v39i8.1716

Gao, L., Cai, N., Fu, X., He, R., Zhang, H., Zhou, J., Kuang, D., and Liu, S., 2021. Influence of PPA on the Short-Term Antiaging Performance of Asphalt. Advances in Civil Engineering, 2021, pp.1-11. Doi:10.1155/2021/6628778.

Ge, D., Yan, K., You, L., and Wang, Z., 2017. Modification mechanism of asphalt modified with Sasobit and Polyphosphoric acid (PPA). Construction and Building Materials, 143, pp.419-428. Doi:10.1016/j.conbuildmat.2017.03.043

Hamdou, H.M., Ismael, M.Q., and Abed, M.A., 2014. Effect of Polymers on Permanent Deformation of Flexible Pavement. Journal of Engineering, 20(12). pp.150-166. Doi:10.31026/j.eng.2014.12.10

Hilal, M., 2023. Evaluation of Modified Asphalt Binder and Mixtures with Polyphosphoric Acid. Al-Nahrain Journal for Engineering Sciences, 26(1), pp.31-36. Doi: 10.29194/NJES.26010031

Huang, S.C., Turner, T.F., Miknis, F.P., and Thomas, K.P., 2008. Long-term aging characteristics of polyphosphoric acid-modified asphalts. Transportation Research Record, 2051(1), pp.1-7. Doi:10.3141/2051-01

Ismael, M.Q., and Al-Harjan, R.F.A., 2018. Evaluation of Job-Mix Formula Tolerances as Related to Asphalt Mixtures Properties. Journal of Engineering, 24(5), pp.124-144. Doi: 10.31026/j.eng.2018.05.09.

Ismael, M.Q., 2022. Chemical and rheological properties of reclaimed asphalt binders modified by waste engine oil. Innovative Infrastructure Solutions, 7(2), p.136. Doi:10.1007/s41062-022-00751-w

Jafari, M., and Babazadeh, A., 2016. Evaluation of polyphosphoric acid-modified binders using multiple stress creep and recovery and linear amplitude sweep tests. Road Materials and Pavement Design, 17(4), pp.859-876. Doi:10.1080/14680629.2015.1132631

Jaroszek, H., 2012. Kwas polifosforowy w modyfikacji asfaltów drogowych. Chemik, 66(12), pp.1340-1345.

Khader, G.A., Ramesh, A., and Kumar, M., 2015. A laboratory study on acid modified bituminous mixes in comparison for rutting characteristics. Civil Engineering and Urban Planning: an International Journal, 2(4), pp.19-33.Doi:10.5121/civej.2015.2403.

Kodrat, I., Sohn, D., and Hesp, S.A., 2007. Comparison of polyphosphoric acid-modified asphalt binders with straight and polymer-modified materials. Transportation Research Record, 1998(1), pp.47-55. Doi:10.3141/1998-06

Lesueur, D., 2009. The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification. Advances in colloid and interface science, 145(1-2), pp.42-82. Doi:10.1016/j.cis.2008.08.011

Lim, C.S., Jang, D.S., Yu, S.M., and Lee, J.J., 2022. Analysis of the properties of modified asphalt binder by FTIR method. Materials, 15(16), P.5743.‏ Doi:10.3390/ma15165743

Masson, J.F., and Collins, P., 2009. FTIR study of the reaction of polyphosphoric acid and model bitumen sulfur compounds. Energy & fuels, 23(1), pp.440-442. Doi:10.1021/ef800582j

Olabemiwo, O. M., Esan, A. O., Adediran, G. O., and Bakare, H. O., 2016. The performance of Agbabu natural bitumen modified with polyphosphoric acid through fundamental and Fourier transform infrared spectroscopic investigations. Case Studies in Construction Materials, 5, pp. 39-45. Doi:10.1016/j.cscm.2016.06.003

Poorna, R. L., Mymoon, M., and Hariharan, A., 2014. Preservation and protection of traditional knowledge–diverse documentation initiatives across the globe. Current Science, pp. 1240-1246. ‏https://www.jstor.org/stable/24107164

Ramasamy, N.B., 2010. Effect of polyphosphoric acid on aging characteristics of PG 64-22 asphalt binder. University of North Texas. https://digital.library.unt.edu/ark:/67531/metadc33196/manifest/

Raof, H. B., and Ismael, M. Q., 2019. Effect of Polyphosphoric Acid on rutting resistance of asphalt concrete mixture. Civil Engineering Journal, 5(9), pp.1929-1940.‏ Doi:10.28991/cej-2019-03091383.

Sarsam, S. I., and Lafta, I. M., 2014. Assessment of modified-asphalt cement properties. Journal of Engineering, 20(06), pp.1-14.‏ Doi:10.31026/j.eng.2014.06.01

SCRB/R9. 2003. General Specification for Roads and Bridges. Section R/9, Hot-Mix Asphalt Concrete Pavement, Revised Edition. State Corporation of Roads and Bridges, Ministry of Housing and Construction, Baghdad, Republic of Iraq.

Taher, Z.K., and Ismael, M.Q., 2023. Moisture Susceptibility of Hot Mix Asphalt Mixtures Modified by Nano Silica and Subjected to Aging Process. Journal of Engineering, 29(4), pp.128-143. Doi:10.31026/j.eng.2023.04

Yan, K., Zhang, H., and Xu, H., 2013. Effect of polyphosphoric acid on physical properties, chemical composition and morphology of bitumen. Construction and building materials, 47, pp.92-98.Doi:10.1016/j.conbuildmat.2013.05.004.

Yu, J.Y., Feng, P.C., Zhang, H.L., and Wu, S.P., 2009. Effect of organo-montmorillonite on aging properties of asphalt. Construction and Building Materials, 23(7), pp.2636-2640.Doi:10.1016/j.conbuildmat.2009.01.007

Zhang, F., Hu, C., and Zhang, Y., 2018. Influence of poly (phosphoric acid) on the properties and structure of ethylene–vinyl acetate‐modified bitumen. Journal of Applied Polymer Science, 135(29), p.46553.Doi:10.1002/app.46553.

Zhang, F., Hu, C., and Zhang, Y., 2018. Research for SEBS/PPA compound‐modified asphalt. Journal of Applied Polymer Science, 135(14), p.46085.‏ Doi:10.1002/app.46085

Zhang, H., Chen, Z., Xu, G., and Shi, C., 2018. Physical, rheological and chemical characterization of aging behaviors of thermochromic asphalt binder. Fuel, 211, pp.850-858.Doi:10.1016/j.fuel.2017.09.111

Similar Articles

You may also start an advanced similarity search for this article.